Product ID:1,1-DICHLOROETHANE SOLUTION, EPM50113
MSDS Date:08/05/1994
FSC:6810
NIIN:00N064965
MSDS Number: CBVZY

EM SCIENCE

480 DEMOCRAT RD
GIBBSTOWN, NJ 08027
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 609-354-9200

Cage: DO242

EM SCIENCE

70 GIBBSTOWN, NJ 08927 US

Telephone: 800-424-9300 (CHEMTREC)

Cage: DO242

ETHANE, 1,1-DICHLORO-; (1,1-DICHLOROETHANE) (SARA 313)

CAS: 75-34-3

RTECS: KI0175000

Fraction By Weight: 0.02%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 99.98%

OSHA PEL S, 200 PPM

ACGIH TLV: S,200PPM/250STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TOXIC BY INGESTION AND INHALATION. CAN
BE TOXIC BY SKIN ABSORPTION. AFTER INGESTION OR INHALATION, INITIAL
SYMPTOMS MAY BE ONLY THAT OF MILD INTOXICATION, BUT MAY BECOME
SEVERE AFTER 1-18 HRS. AFFECTS CNS, ESP OPTIC NERVE.
CHRONIC:MARKED IMPAIRMENT OF VISION & ENLARGEMENT OF LIVER HAS BEEN
REPORTED W/(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:CHRONIC EXPOS. CHRONIC EXPOS MAY ALSO
CAUSE DMG TO KIDNEYS & CNS. CAUSES DIZZ, NAUS, MUSCLE WEAK,
NARCOSIS, RESP FAILURE. INGEST CAN PRDCE BLINDNESS (AS LITTLE AS 30
ML)/DEATH (AS LITTLE AS 100 ML). PRLNGD/RPTD SKIN CONT MAY CAUSE
IRRIT. FETAL DEVELOPMENT ABNORMS & EFTS ON EMBRYO/FETUS HAVE BEEN
(SUPP DATA)
Medical Cond Aggravated by Exposure:SKIN CONDITIONS, EYE PROBLEMS,
IMPAIRED LIVER OR KIDNEY FUNCTION.

First Aid:GET MED ASSISTANCE FOR ALL CASES OF OVEREXP. SKIN:IMMED FLUSH
THORO W/LG AMTS OF WATER. REMOVE CONTAM CLOTHES AND WASH BEFORE
REUSE. EYES:IMMED FLUSH THORO W/WATER FOR @ LST 15 MIN.
INHAL:REMOVE TO FR ESH AIR; GIVE ARTF RESP IF BRTHG HAS STOPPED.
INGEST:IF CONSCIOUS, DRINK WATER & INDUCE VOMIT IMMED AS DIRECTED
BY MED PERS. NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERSON.

Flash Point Method:TCC
Flash Point:52.0F,11.1C
Lower Limits:6.7%
Upper Limits:36.5%
Extinguishing Media:USE WATER SPRAY, FOAM, DRY CHEMICAL, OR CO*2.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:DANGEROUS FIRE AND EXPLOSIVE HAZARD.
CLOSED CONTAINERS MAY EXPLODE UPON HEATING. VAPOR CAN TRAVEL
DISTANCES TO IGNITION SOURCE AND FLASH BACK.

Spill Release Procedures:WEAR SUITABLE PROT EQUIP LISTED IN CTL
MEASURES. ELIM ANY IGNIT SOURCES UNTIL AREA IS DETERM TO BE FREE
FROM EXPLO/FIRE HAZS. CNTN RELS & ELIM IT SOURCE, IF THIS CAN BE
DONE W/OUT RISK. DISP AS HAZ WA STE. COMPLY W/FED, STATE & LOC
REGS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE IN A COOL
AREA AWAY FROM IGNITION SOURCES AND OXIDIZERS. DO NOT BREATHE VAPOR
OR MIST. DO NOT GET IN EYES, ON SKIN/CLTHG.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:IF WORKPLACE EXPOS LIM(S) OF PROD/ANY COMPONENT
IS EXCEEDED (SEE TLV/PEL), NIOSH/MSHA APPRVD AIR SUPPLIED RESP IS
ADVISED IN ABSENCE OF PROPER ENVIRON CTL. ENGINEERING &/OR ADMIN
CTLS SHOULD BE IMPLEM ENTED TO REDUCE EXPOS.
Ventilation:MATL SHOULD BE HANDLED OR TRANSFERRED IN AN APPROVED FUME
HOOD OR WITH ADEQUATE VENTILATION.
Protective Gloves:BUTYL RUBBER, VITON OR EQUIVALENT.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT TAKE
INTERNALLY.
Supplemental Safety and Health
EFTS OF OVEREXP:REPORTED FROM PROLONGED EXPOSURE TO METHYL ALCOHOL IN
LABORATORY TESTS INVOLVING PREGNANT RATS.

Boiling Pt:B.P. Text:149F,65C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:97 @ 20C
Vapor Density:1.1
Spec Gravity:0.791 (H*2O=1)
Evaporation Rate & Reference:5.9 (BUAC=1)
Solubility in Water:SOLUBLE
Appearance and Odor:CLEAR LIQUID.
Percent Volatiles by Volume:99.9 +

Stability Indicator/Materials to Avoid:YES
ACIDS, OXIDIZERS, REACTIVE METALS.
Stability Condition to Avoid:HEAT; CONTACT WITH IGNITION SOURCES.
Hazardous Decomposition Products:CO*X, FORMALDEHYDE.

Waste Disposal Methods:DISPOSE AS HAZARDOUS WASTE. COMPLY WITH FEDERAL,
STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.